Zion Baptist Church was constituted on August 5, 1826 with ten charter members. Conference was called for the purpose of electing delegates to the Yellow River Association and the election of two deacons. A pastor was called to serve one Sunday each month.
During the early years of ZBC, slaves were received into the church. The minutes recorded,
"The following joined our church by experience from September 4, 1826 till September 14, 1826: 30 white males and females and 3 blacks. One black, Sam Persall, felt the call to preach. After examination and hearing him preach from Zion’s pulpit, he was licensed to preach."
In 1840, Zion joined the Rock Mountain Association, which merged with Appalachia at a later date. A letter to the Stone Mountain Association is mentioned in 1872. No definite date is given when joining this Association. Always a Missionary Baptist church, the record shows donations being sent to Mercer University, and yearly support was sent to Foreign, Home, and Indian Missions.
The Civil War caused a hardship on Zion in that the Yankee raids separated Zion from their pastor. The December 30th conference states a resolution:
"that we sympathize with our pastor in being cut off from us by Yankee raids and rejoice to meet with him once more at Old Zion."
After the war, slaves were given their freedom, and Zion sold the church building to them a few days later.
In 1869, a new church building was built on a track of land donated by Mr. Thomas Hicks and Mr. Thomas Black, at the crossroads of Highways, 20 and 212, which is our present location. It was a day of thanksgiving when Zion could finish a pastorium and call a pastor for full-time service in the community.